About Polystyrene

Polystyrene is one of the most widely used plastics in the world. Understanding its properties, types, and lifecycle is the first step toward making informed recycling decisions.

Learning about polystyrene and its properties

What is Polystyrene?

Polystyrene is a versatile synthetic polymer made from styrene monomer, classified under resin code #6. It is a thermoplastic, meaning it can be repeatedly melted and reformed without significant degradation.

First discovered in 1839 by Eduard Simon, a German apothecary, polystyrene remained a laboratory curiosity until commercial production began in the 1930s. It quickly became one of the most produced plastics globally.

The brand name Styrofoam is actually a registered trademark of Dow Chemical Company, specifically for their extruded polystyrene (XPS) insulation product. The white foam cups and containers commonly called "Styrofoam" are actually expanded polystyrene (EPS), a different product entirely.

Resin Code#6 (PS)
TypeThermoplastic Polymer
Discovered1839 by Eduard Simon
Commercial Production1930s (BASF/Dow)
CompositionCarbon and Hydrogen (C8H8)n
Melting Point~240 degrees F (115 degrees C)
Density (EPS)15-30 kg/m3 (95% air)

EPS vs XPS

The two main forms of polystyrene foam have distinct properties and recycling challenges.

EPS

Expanded Polystyrene

moderate

The familiar white, lightweight foam made of pre-expanded polystyrene beads fused together. Contains up to 98% air, making it extremely lightweight but bulky. Most commonly seen in disposable cups, food containers, and packaging peanuts.

Characteristics

98% air by volumeWhite, beaded appearanceVery lightweightGood insulation propertiesBrittle and breaks into beadsResin identification code #6Floats on waterPoor UV resistance

Common Uses

  • Disposable coffee cups
  • Food takeout containers
  • Packaging peanuts
  • Protective product packaging
  • Coolers and ice chests
  • Seedling trays
  • Craft and hobby materials
  • Insulated shipping containers
XPS

Extruded Polystyrene

difficult

A denser, more rigid foam produced through an extrusion process. Typically colored (blue, pink, or green depending on manufacturer). Primarily used in construction for insulation boards and structural applications.

Characteristics

Denser than EPSSmooth, uniform cell structureColored (blue/pink/green by brand)Higher compressive strengthBetter moisture resistanceExcellent thermal insulationMore UV resistant than EPSClosed-cell structure

Common Uses

  • Building insulation boards
  • Foundation waterproofing
  • Roofing insulation
  • Cold storage facilities
  • Crafting and modeling
  • Structural insulated panels
  • Highway and bridge construction
  • Geotechnical fill material

Where It's Found

Polystyrene is used in a wide range of everyday products and industrial applications.

Cups & Containers

Disposable coffee cups, food takeout containers

Protective Packaging

Product cushioning, shipping materials

Building Insulation

Wall and roof insulation panels

Food Containers

Meat trays, egg cartons, deli containers

Coolers & Ice Chests

Portable coolers, cold chain packaging

Medical Supplies

Lab trays, medical packaging, test kits

Electronics

TV and computer protective packaging

Construction

ICF forms, geofoam, decorative molding

Industry at a Glance

$0.7B
US Market Value
Annual market for recycled polystyrene products
32%
Recycling Access
Of Americans have access to PS recycling
12+
State Bans
States with polystyrene restrictions
15M
Tons/Year
Global annual polystyrene production

How Polystyrene is Made

The manufacturing process from raw petroleum to finished polystyrene products.

1

Raw Material

Styrene monomer is derived from petroleum through the dehydrogenation of ethylbenzene.

2

Polymerization

Styrene monomer undergoes polymerization to create solid polystyrene beads or pellets.

3

Expansion (EPS)

For EPS, beads are impregnated with pentane gas and then expanded with steam to 40-50x their original volume.

4

Molding

Expanded beads are molded into final shapes using steam chests and custom molds under controlled conditions.

5

Extrusion (XPS)

For XPS, polystyrene is melted and forced through a die with a blowing agent to create dense, uniform foam boards.

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